ABSTRACT Hyperspectral standoff detection systems such as Focal Plane Array (FPA) Fourier Transform Infrared (FTIR) spectrometers provide high spatial resolution in detecting airborne chemical contaminants that are invisible to the human eye but potentially hazardous. When two such systems are operated simultaneously with a suitable opening angle, they enable tomographic reconstruction of contaminant plumes with improved spatial and temporal accuracy. This work presents a mathematical model of these measurement capabilities and an algorithm to identify, localize, and quantify contaminant release sources. The objective is to develop a tool that reconstructs release locations and predicts the future plume evolution from standoff measurement data, thereby supporting early warning and situational awareness in hazardous material release scenarios. The transport of contaminants is modeled by an advection–diffusion equation, and the corresponding inverse problem for source identification is formulated accordingly. Owing to the severe ill‐posedness and underdetermination of the problem, a sparsity‐promoting regularization approach is employed together with a high‐performance optimization algorithm. To incorporate the tomographic measurement data into the discrete formulation, a level‐set description of a threshold concentration is used, allowing the measurements to be represented independently of the computational mesh and avoiding costly remeshing procedures.
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