Studying how fine-tuning shapes refusal and noncompliance behaviour requires knowing which training examples refuse or otherwise fail to fulfil the request. Existing annotations cover evaluation sets, which are far smaller than training corpora. We present CompOrca, compliance labels for all 4,233,923 examples of the OpenOrca corpus. Every example was classified as compliant or noncompliant by five passes of an open-weight LLM judge (LongCat-2.0, 1.6T parameters). The corpus is released as unanimous compliance (94.75%), unanimous noncompliance (1.28%), and nonunanimous rows (3.97%), with the raw vote counts. A single pass flags 2.7-3.2% of the corpus as noncompliant, while only 1.28% is flagged by all five, so the most ambiguous rows can be filtered out. Against 450 human-annotated examples (150 annotated twice; human-human $\kappa=0.93$), the unanimous compliance and noncompliance labels are 97.3% and 86.7% precise. The noncompliance label is a high-precision subset of the corpus's noncompliance. Published refusal-detection methods recall between 0.4% and 94.1% of human-labelled noncompliance. We release the full corpus with its per-row labels and vote counts at https://huggingface.co/datasets/cemiu/CompOrca
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