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Oct 2026

Photoinduced metal-free cascade silylation/cyclization of alkynes/alkynones with hydrosilanes to access 3-silylated benzothiophenes and thioflavones.

A metal-free photocatalytic method for the synthesis of silylated thioflavones and benzothiophenes has been established through cascade silylation/cyclization of alkynes/alkynones with hydrosilanes. This transformation features mild reaction conditions, excellent functional group compatibility, and broad substrate scop...

Yun-Fei Tian, Wei-Jun Fu, Zhi-Qiang Wang et al. · 0 citations
Sep 2026

Iron-catalyzed hydroalkylation of quinoxalin-2(1H)-ones with alkenes and phenylsilane.

A practical protocol has been established for the synthesis of dihydroquinoxalin-2(1H)-ones through iron-mediated hydroalkylation of quinoxalin-2(1H)-ones with alkenes and phenylsilane. The reaction proceeds smoothly at room temperature, utilizing alkenes as the alkylating agents and phenylsilane as the hydride source,...

Lei-Lei Wang, Juan-Juan Wu, Shu-Hong Dong et al. · 0 citations

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