We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes'principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.
Quantum mechanics is widely recognised as being incomplete. It is not consistent with the second law of thermodynamics and does not provide a scientifically credible physical account of the measurement process, the means by which coherence is broken and classically observable states are recorded. This has led to many ad hoc assumptions being used to account for various properties of quantum systems, among which is the coherence time of quantum devices that determines their ability to perform computations. Here, we show that all these properties can be accommodated naturally and consistently in the context of non-integrable mixing quantum systems which exhibit continuous spectra, as arises in the thermodynamic limit of large systems. In particular, for isolated systems we show that the time-reversal symmetry associated with unitary time evolution of the quantum state gives rise to time-symmetry breaking and a semi-group evolution which attains thermodynamic equilibrium at long times. Moreover, the emergence of this non-unitary time-asymmetry leads to microcanonical equilibrium states in which all quantum coherence is lost and is accompanied by the transformation of pure states into mixtures, leading in turn to an increase in entropy. Inclusion of a macroscopic measurement apparatus shows how the outcome of a measurement corresponds to the von Neumann projection postulate, arising with probabilities in conformance with the Born rule. The mathematical structure of the theory which applies to quantum systems with continuous spectra is closely analogous to the classical ergodic theory of dynamical systems and the conditions under which they attain equilibrium states.
When only local observables of a many-body quantum system are of interest, it is desirable to formulate a reduced description within the Hilbert space of the corresponding subsystem, with the remaining degrees of freedom traced out and acting as an environment. Assuming initially uncorrelated states and Gaussian environments, we develop a framework for reconstructing the local dynamical generator of noninteracting quantum chains, with polynomial computational complexity. As an application, we consider two representative models: a bipartitioned Kitaev chain and a Kitaev chain boundary-coupled to a fully connected free-fermion environment. In both models, strong subsystem-environment coupling leads to non-Markovian dynamics characterized by ballistic spreading of the Lindblad dissipator support within the subsystem. On the other hand, weak coupling to a fully connected environment yields predominantly boundary-localized, Markovian dissipation. Our work highlights the implications of subsystem-environment correlations on the generator of local dynamics, beyond the conventional weak-coupling approximations.
Markovian open-system dynamics have widespread applications throughout quantum information science, including algorithmic state preparation. Their convergence is commonly quantified using the worst case global trace distance between the evolving and stationary states. However, this criterion can be unnecessarily stringent when only physically relevant observables are of interest. Here we introduce and study observable-specific mixing times. We prove that, for quasi-local, rapidly mixing Lindbladians, sums of geometrically local observables equilibrate in a time independent of system size, in contrast to the logarithmic dependence of global state mixing. This separation reduces the runtime of dissipative quantum algorithms, including quantum Gibbs samplers, for estimating quantities such as the Gibbs state energy and local order parameters, yielding an overall scaling that is linear in system size. Complementing this quantum result, we develop a quantum-inspired classical algorithm for estimating the same quantities. Its runtime is likewise linear in system size, but scaling exponentially in $\mathcal{O}\big(\log(1/\epsilon)^D\big)$, where $D$ denotes the spatial dimension of the lattice. We further analyse non-interacting Lindbladians over qudits, fermions, and bosons, demonstrating that locality of observables is not always necessary for a qualitatively faster mixing. Small-scale simulations of quantum Gibbs samplers reveal no large hidden constants in our asymptotic analysis and show that the theoretical predictions closely capture the finite-size dynamics.
Štěpán Šmíd, Richard Meister, Mario Berta et al.· 0 citations
Rare fluctuations in physical systems depend on the detailed microphysics responsible for the fluctuations. In classical statistical systems, the large deviation principle has elucidated the role of semi-classics in describing this regime, and has simultaneously provided a the mathematical foundation of statistical mechanics. Large deviation theory for quantum system is considerably less developed. As all physical systems are fundamentally quantum mechanical, this leaves a major gap in our understanding of rare fluctuations relevant to statistical physics, cosmology, and more. In this paper, we develop the practical aspects of the theory of large deviations relevant for calculating rare events in physical systems from quantum walks to cosmology. We first analyze the case of the anharmonic oscillator coupled to a bath, showing explicitly how the system evolves from dominantly statistical (e.g. thermal) to quantum fluctuations. We then generalize these results, showing that the dominant rare fluctuations minimize the measurement-induced relative entropy. This perspective provides a thermodynamic description of a wide range of open quantum systems. We apply these results to random walks that arise in cosmology through stochastic inflation. We show that the evolution of the density matrix of long wavelength fields on a fixed de Sitter background breaks the KMS symmetry, giving rise to a stationary density matrix that does not respect detailed balance.
Daniel Green, Kshitij Gupta, A. Premkumar· 0 citations
Reverse Physics is a methodology that breaks physical theories into separate mathematical and physical conditions to establish their logical relationships. To showcase the power of the methodology, we present several results for quantum mechanics and their related insights. The standard Hilbert-space formulation conflicts with basic physical requirements, while a minimal topological modification can solve these problems. The ensemble space, rather than the pure-state space, distinguishes classical from quantum systems. The Born rule is an additional assumption linking orthogonality, mutual exclusivity and information entropy. Under explicit background conditions, unitary evolution is equivalent to deterministic and reversible evolution. Nonselective projective measurements can be characterized as Lindblad equilibration processes, while unitary evolution can be characterized as a limit of infinitesimal projective processes. Classical mechanics is recovered as the high-entropy limit of quantum mechanics, and every quantum state, pure or mixed, is a dynamical, spectral and thermodynamic equilibrium. These results are self-contained, use the standard vector-space representation and can thus be used as common tools and constraints for teaching, interpretations, reconstructions and future theories.
G. Carcassi, Tobias Thrien, C. Aidala· 0 citations
Estimation of work at the quantum scale remains a central challenge in quantum thermodynamics. Canonical approaches have a fundamental drawback: they assume classical control of the quantum system, as implicit in a time-dependent Hamiltonian. Yet the energetic cost of implementing this control is omitted and can exceed the system's energy scale by orders of magnitude, calling into question the operational significance of work values. We address this by autonomizing the controlled energy transfer, embedding the driven dynamics into an energy-conserving evolution on a larger quantum system. Work is then unambiguously identified with the energy transferred between the two systems, singling out a unique observable on the driven system: the work operator. We show that the quantum work operator evades a no-go theorem by deriving a quantum fluctuation theorem that recovers the Jarzynski equality in classical scenarios. We incorporate imperfect control and quantify corrections to work statistics. Extending the framework to open quantum systems, we obtain an operatorial first law in which work, heat, and internal-energy changes are represented by distinct operators on the reduced system. Together, these results settle the long-standing debate over whether work is a quantum observable: it is, once the controlling system is included in the description rather than treated as external.
Carlo Cepollaro, Danial Chughtai, Alberto Spalvieri et al.· 2 citations
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