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Conical Intersection-Mediated Nonradiative Decay in an ESIPT-Active Imidazole Derivative.
Excited-state intramolecular proton transfer (ESIPT) is a photoinduced process that involves proton migration within an intramolecular hydrogen-bonded framework following electronic excitation and is often associated with large Stokes-shifted emission. However, the excited-state fate after proton transfer is not exclus...
Spatially programmed polymorphic crystallization via microenvironment design
Organic semiconductor crystals with long-range order and designable properties are pivotal in optoelectronic devices. Organic crystals bonded by weak intermolecular interactions usually follow non-classical crystallization trajectories, yielding polymorphs with distinctive properties but extremely difficult to control....