Macrocycle Size-Controlled Dynamic and Static Chirality in Donor–Acceptor [2]Catenanes
Chiral [2]catenanes, a prominent class of mechanically interlocked molecules (MIMs), can exhibit either static or dynamic mechanostereochemistry. Controlling these mechanostereochemical states without altering the covalent connectivity, however, remains challenging. Herein, we report a series of chiral [2]catenanes d...