Green Light‐Driven, Diastereoselective Synthesis of Pentasubstituted α ‐Trifluoromethylated Pyrrolidines via a Singlet Carbene Process
Trifluoromethylated heterocycles represent privileged structural motifs in pharmaceuticals and agrochemicals, as the incorporation of a CF 3 group significantly enhances metabolic stability, lipophilicity, and bioactivity. Among these, α ‐trifluoromethyl pyrrolidines have garnered considerable interest; however...