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Oct 2026

New Insights into the Decoupling Mechanism of Ion Motion from Segmental Relaxation in Glass-Forming Polymers: The Interplay of Cohesive Energy Density

Decoupling ion transport from segmental motion offers a promising route for solid polymer electrolytes, yet identifying its governing factor, whether the glass transition temperature (Tg), fragility index (m), or dynamic heterogeneity, remains challenging due to their inherent interdependence. Here, we systematically...

Xu-Hong Zheng, Zhen Chen, Ling-Hui Cui et al. · 0 citations
2026

Segmental Dynamics, Ion-Associated Relaxation, and Ion Transport in Cellulose-Based Gel Polymer Electrolytes Revealed by Broadband Dielectric Spectroscopy

: Cellulose-based gel polymer electrolytes (GPEs) are promising sustainable candidates for next-generation lithium batteries; however, the relationship between polymer dynamics and ion transport remains insufficiently understood. In this study, cellulose-based GPEs with varying lithium salt concentrations and crosslink...

Ruo-Xi Zhang, Rong-Zu Sun, Zhou Wei et al. · 0 citations

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