Zr-Oxo Cluster-Based Metal-Organic Framework for Selective C(sp3)-H Bond Photooxidation.
Selective aerobic oxidation of C(sp3)-H bonds to carbonyl compounds is an important but challenging transformation in green and sustainable catalysis, owing to the difficulty of achieving high chemoselectivity while suppressing overoxidation under mild conditions. Herein, we report HEBMU-1, a Zr-oxo cluster-based metal...