F-doped FeNC catalyst with axial ligand engineering: breaking the strong adsorption barrier for efficient non-radical peroxymonosulfate (PMS) activation and antibiotic removal.
Conventional Fe-Nx sites exhibit excessively strong electronic coupling between metal centers and oxygen species during peroxymonosulfate (PMS) activation, which inevitably induces non-selective radical pathways and fundamentally restricts the efficient and selective oxidative degradation of organic pollutants. Herein,...