Vinylene-linked covalent organic frameworks (COFs) are promising photocatalysts because their conjugated sp2-carbon frameworks combine exceptional chemical stability with efficient charge transport. However, the limited reversibility of C═C bond formation narrows the scope of polymerizable monomers, restricting the s...
Ming-Hao Liu, Chen-Sheng Wang, Ying-Guo Li et al.· Journal of the American Chem...· 0 citations
The design of crystalline materials has evolved from the construction of periodic frameworks toward increasingly complex architectures featuring ordered heterogeneity and emergent functions. Despite substantial progress in hybrid crystalline materials, a general framework for understanding hybrid assembly across diff...
Hong Jiang, Wen-Qiang Zhang, Yu-Ting Zhang et al.· Journal of the American Chem...· 0 citations
The construction of highly porous metal–organic frameworks with complex topologies requires precise matching between linker conformation and node connectivity. Here we report the reticular design and synthesis of CU-6-M (M = Fe or Cr), assembled from conformationally adaptive diphenylethynyl linkers and six-connect...
Xu Chen, L. H. Wee, Mohammad Reza Alizadeh Kiapi et al.· Nature Synthesis· 0 citations
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