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Ying-Chun Chen

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Oct 2026

Gold(I)-Catalyzed Asymmetric Transformations of 1-(1-Alkynyl)cyclobutyl Ketones: Access to Enantioenriched Cyclopenta[ b ]furans Bearing Vicinal Bridged Quaternary Stereocenters

Present herein is a gold(I)-catalyzed asymmetric cascade reaction of 1-(1-alkynyl)cyclobutyl ketones. Upon activation by a chiral phosphoric-acid-tethered gold(I) complex, they undertake intramolecular 5-endo-dig cyclization, and the resulting oxocarbenium species engage in an asymmetric 1,2-alkyl migration to genera...

Bao-Rui Kong, Shi-Cun Li, Qiao-Yang Liu et al. · 0 citations

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