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Oct 2026

Triplet Resting States Govern E / Z Selectivity and Chemoselectivity in Carbene-Pincer Cobalt-Catalyzed Alkyne Semihydrogenation

Rigid, electronically tunable carbene-based pincer ligands constitute a highly promising platform for controlling selectivity in cobalt-catalyzed alkyne semihydrogenation, but the influence of catalyst spin-state characteristics on Z/E selectivity and over-reduction remains poorly understood. Herein, we compare the m...

Zi-Han Zhang, Yong-Fang Zhang, Yi Gao et al. · 0 citations

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