Organocatalytic Dynamic Kinetic Resolution for the Stereoconvergent Synthesis of N-N Axially Chiral Compounds.
Dynamic kinetic resolution (DKR) serves as a fundamental approach in asymmetric synthesis which enables the efficient conversion of racemic starting materials into a single stereoisomer, yet its extension to racemic diastereomers remains a formidable challenge, and reported DKR processes have largely been restricted to...