Vanadium-based thiophosphates in the MPQ3/M2P2Q6 family provide an unusual platform for coupling mixed-metal valence, metal vacancies, and 2D magnetism, but access to phase-pure multimetal solid solutions with verified chemical homogeneity remains limited. Here, we show that multication alloying provides a route to i...
Patricia E. Meza, T. Slade, Adam Balvanz et al.· Chemistry of Materials· 0 citations
: Understanding how unusual oxidation states influence material properties is important for both fundamental science and energy applications. AgSnSe 2 is particularly intriguing because it stabilizes the rare and long-debated Sn 3+ oxidation state, whose true existence and role have remained enigmatic for many years. I...
M. Kanatzidis, Paribesh Acharyya, Yu-Kun Liu et al.· Research Square· 0 citations
The MCP provides a bounded, testable, and reproducible foundation for closed-loop agentic instrumentation research by connecting local LLMs to scientific instruments through the Model Context Protocol.
In chemically complex multimetal systems, how local coordination asymmetry emerges and propagates to define the bulk structural behavior remains fundamentally unresolved. In high-entropy metal-organic frameworks (MOFs), long-range crystallographic order coexists with intrinsic chemical disorder, yet a quantitative rela...
Rajan R. Bhawnani, P. K. Reddy, Meagan R Phister et al.· Journal of the American Chem...· 0 citations
Bridging atomically precise materials design with scalable membrane manufacturing remains a central challenge in separation science. Two-dimensional covalent organic frameworks (2D COFs) offer tunable porosity and chemistry, but poor crystallinity and processability have limited their performance in membranes. Here we...
Jasasmita Das, Yun Kyung Shin, Beatrice Bartolomei et al.· Journal of the American Chem...· 0 citations
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