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Tong Gao

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Sep 2026

Radical Stabilization-Driven Reactivity in Paracyclophane Ketoesters: Site-Selective Hydrogen Atom Transfer over Norrish Fragmentation

We report a radical-stabilization-driven photoreactivity of [2,2]paracyclophane (PCP) ketoesters that enables site-selective hydrogen atom transfer (HAT) under visible-light irradiation. The PCP ketoester enables free-radical photopolymerization under air, deep curing, and low toxicity. In combination with an iodoniu...

Maxime Michelas, Tong Gao, Kaidan Yang et al. · 0 citations

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