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Tomohiro Noguchi

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Open access Oct 2026

A Pyridoxal 5'-Phosphate-Dependent Decarboxylative Mannich Reaction Initiates Construction of the Nonpeptidic Scaffold of Kaitocephalin.

These results identify KpbH as the first native PLP-dependent enzyme that catalyzes an l-aspartate-dependent decarboxylative Mannich-type C-C bond-forming reaction and reveal a biosynthetic strategy for constructing a noncanonical amino acid-like C-C bond scaffold.

Tomohiro Noguchi, Yukari Maeno, Kazuo Furihata et al. · 0 citations

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