Author

Tatiana N. Petrushina

2 papers indexed here

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Sep 2026

Synthesis of Rhodium and Ruthenium Pi-Complexes with Pendant Amide Substituents for Intramolecular Proton Transfer upon Activation of C–H Bonds

Cyclopentadienyl and arene complexes with pendant amide substituents [(C5Me4CH2CH2NHR)RhCl2]n and [(C6H5CH2CH2NHR)RuCl2]n (R = COCF3, Ts) were synthesized by heating the corresponding dienes with metal chlorides. They were tested as catalysts for the annulation of N-methoxy-p-methylbenzamide with alkynes. Contrary to...

Tatiana N. Petrushina, Alevtina S. Voskresenskaia, Roman A. Pototskiy et al. · Organometallics · 0 citations

Open access Aug 2026

Relative Stability of Metal Complexes with Various Diene Ligands: Experimental and Computational Study

The binding strength of various dienes was established by NMR investigation of ligand exchange reactions in (diene)Rh(acac) complexes. The binding affinity decreases in the following order: tetraphenyl-cyclopentadienone >1,5-cyclooctadiene > norbornadiene > tetrafluoro-benzobarrelene > dimethyl-tetrafluoro-benzobarre...

Tatiana N. Petrushina, Nikita M. Ankudinov, D. Perekalin · Organometallics · 0 citations