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Author

Takahisa Ikeue

2 papers indexed here

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Sep 2026

Expanded coordination cavity stabilizes a high-spin Fe(III) state in a six-coordinate oxypyriporphyrin with mixed neutral/anionic axial ligation.

Oxypyriporphyrin (OxyPyP) possesses an unusually expanded N4 coordination cavity, yet its influence on the electronic structures of coordinated metal ions remains poorly understood. Herein, we investigate a series of OxyPyHEP-Fe(III) complexes with different axial-ligation environments to clarify how the expanded coord...

Hiroto Takeshita, Yuki Ide, Shigeki Mori et al. · 0 citations
Sep 2026

Selective photodegradation of G-quadruplex DNA by a cationic zinc phthalocyanine: role of binding geometry.

The selective photodegradation of G-quadruplex DNA (GQ) was investigated using the cationic zinc phthalocyanine ZnPc as a photosensitizer. UV-Vis absorption titration suggests that electrostatic interactions contribute to ZnPc association with both duplex and G-quadruplex DNA, whereas 1H NMR analysis indicates that one...

Shiori Homma, Ryo Karita, Taka-aki Ishibashi et al. · 0 citations

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