Nanoparticle-Enabled Interfacial Kinetic Control of Bond-Exchange Reactions: Insights from Biomedical Poly(ε-caprolactone)-Based Dynamic Polymers
This perspective establishes NP–dynamic polymer interfaces as a programmable kinetic design parameter for controlling bond-exchange reactions in dynamic polymer networks, opening a pathway toward spatially defined covalent adaptable materials with application-specific and programmable dynamic behavior.