S. J. de Carvalho

Role of oscillatory solvent-mediated interactions for the differential capacitance of an electric double layer.

Solvent-mediated ion-ion interactions in aqueous electrolytes often exhibit damped oscillations arising from hydration-shell structuring, yet their consequences for electric double-layer behavior remain poorly quantified. Here, we combine canonical Monte Carlo simulations with a generalized Poisson-Helmholtz-Boltzmann...