Author

R. Popov

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Open access Aug 2026

Pd-Catalyzed Regio‑, Diastereo‑, and Enantioselective Construction of Vicinal Tertiary Stereocenters from Cyclic Allylboronate Salts and Allyl Electrophiles

A regio-, diastereo-, and enantioselective Pd-catalyzed allylation of the lithium salts of 6-membered cyclic allylboronates is reported. The system relies on the use of a commercially available C 2-symmetric chiral bisphosphine ligand and gives access to borylated 1,5-dienes featuring vicinal 3,4-cis tertiary stereocen...

R. Popov, Cheng Zhang, Laure Guénée et al. · JACS Au · 0 citations

Open access Aug 2026

Triterpene Glycosides from the Sea Cucumber Ocnus glacialis Display Cytotoxic and Colony-Inhibiting Activity Against Cancer Cells

The colony formation assay reveals a latent sensitivity of cancer cells—not only to the membranolytic action of triterpene glycosides, but also to the effects of these compounds relevant to other aspects of cell survival, division, and spread.

A. Silchenko, E. Chingizova, E. Menchinskaya et al. · Marine Drugs · 0 citations