Metal–Organic Frameworks for Dinitrogen Reduction to Ammonia: Active-Site Engineering, Mechanistic Pathways, and Reliability Challenges
Metal–organic frameworks (MOFs) provide a highly tunable platform for artificial dinitrogen reduction to ammonia because metal nodes, organic linkers, defects, pore environments, and interfaces can be engineered at molecular and atomic levels. This review critically examines MOF-based electrocatalytic and photocataly...