Author

Paul H. Oyala

2 papers indexed here

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Sep 2026

Co(0)-Arene Complexes Derived from a Co4 Cluster: Synthesis, Characterization, and Hydrogenation Catalysis

Low-valent cobalt complexes have emerged as effective earth-abundant pre-catalysts for olefin hydrogenation reactions. Here, we report a series of heteroleptic Co(0) arene cyclic (alkyl)(amino)carbene (CAAC) complexes that catalytically hydrogenate olefins. Whereas direct reduction of CAACCo(II) precursors affords pr...

Graden Snyder, Joshua Thedford, C. Andre et al. · Inorganic Chemistry · 0 citations

Sep 2026

Experimentally Validated Cobalt Phosphinothiolate Hydride Intermediate Governs the Selectivity Switch between Formate and Syngas in CO2 Reduction

Controlling product selectivity in homogeneous electrocatalytic CO2 reduction remains a significant challenge, often requiring complicated catalyst redesigning. Herein, we identify and validate a cobalt-hydride intermediate that governs the selectivity switch for CO2 reduction to either formate or synthesis gas (syng...

David A. Velazquez, Adya A. Mahapatra, Sevak T. Pogosyan et al. · ACS Catalysis · 0 citations