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Author

O. Godwin

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Oct 2026

Photoinduced C-Br bond cleavage enables difluoroketene-mediated ground-state [2 + 2] cycloaddition: a TD-DFT study.

This work presents a TD-DFT computational study of the visible-light-driven [2 + 2] cycloaddition between alkynes and bromodifluoroacetylsilanes, leading to gem-difluorocyclobutenones. Visible-light irradiation of bromodifluoroacetylsilanes was recently shown by Zhou et al. to generate difluoroketene in situ for [2 + 2...

Cristian J. Guerra, Leandro Ayarde-Henríquez, O. Godwin et al. · 0 citations

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