σ- and π-hole interactions of iodotrifluoroethylene (C2F3I) with tertiary amines characterized by matrix isolation IR spectroscopy.
Under matrix isolation conditions, weakly bound complexes can be stabilized and even higher energy species can be kinetically trapped and subsequently characterized spectroscopically. Halogen bonded and π-hole complexes of iodotrifluoroethylene and different tertiary amines are identified in pH2 matrices. For ITFE-trim...