Confined Mg2+-Directed Interfacial Evolution of Primary Structural Units of Mg-MOF-74 on Platelet Clinoptilolite for CO2/CH4, CH4/N2, and CO2/N2 Separations
Controlling MOF nucleation on zeolite surfaces remains challenging when metal ions are freely supplied in solution, often resulting in poorly regulated interfaces. Herein, Mg2+-exchanged platelet clinoptilolite (Mg-PCP) was used as a confined metal source to direct the in situ growth of Mg-MOF-74-related sol–gel specie...