Author

N. Arulsamy

2 papers indexed here

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Open access Aug 2026

Oxonium-Embedded Benzo[b]perylene: A Redox-Switchable Closed-Shell π‑Cation, and Its Paramagnetic Charge-Transfer Salt with TCNE•–

Organic cations and radicals are promising building components for organic optoelectronics, spintronics and quantum information processing. Realizing their full potential requires strategies to enhance their stability and precisely control their solid-state organization. Herein, we describe a modular synthetic strategy...

Chao Duan, Yuan Xue, D. Straus et al. · ACS Central Science · 1 citation

Open access Sep 2026

From oxido-bridged dimers to hydrogen-bonded assemblies: steric control of self-assembly in cis-dioxovanadium(v) Schiff-base complexes

cis-Dioxidovanadium(v) (cis-VO2+) moieties are among the most fundamental structural units in vanadium(v) coordination chemistry, yet the factors governing their nuclearity, self-assembly, and crystallization remain poorly understood. Here, we investigate these factors in a family of cis-VO2+ Schiff-base complexes deri...

Eric J. Shepard, Andrew C. Bates, C. J. Chang et al. · Dalton Transactions · 0 citations