Kinetic Programming of Dynamic Covalent Networks via Isomer-Pure Diels-Alder Kinetics.
The precise control of material properties through molecular-level architecture remains an enormous challenge in materials science. Here, we present a platform for the kinetic programming of covalently cross-linked networks by translating selective cycloreversion kinetics of isomer-pure endo- and exo-Diels-Alder (DA) d...