Scaling of Nanoalloy Phase Transitions: Elucidating the Distinct Role of Surface Sites
Nano-size-induced shifts in alloy phase-separation critical temperatures (TCnano) are investigated by introducing an atomistic concept of site-specific contributions to the shift (SSCS) associated with different atomic coordination environments in cuboctahedral and truncated-octahedral nanoparticles (NPs). TCnano previ...