Ultramicropore-Matched Molecular Transport in Low-Loading Mixed-Matrix Membranes via Trace-Oxygen-Mediated Thermal Reorganization.
The complementary structural tunability of polymers of intrinsic microporosity (PIMs) and metal-organic frameworks (MOFs) redefines the design space for engineering precise transport channels in mixed-matrix membranes (MMMs). Herein, we present that trace-oxygen-mediated thermal reorganization (TOTR) of PIM-1 micropore...