A Dynamic Surface Metal‐Organic Framework Electrocatalyst: Potential‐Driven Activation of Atomically Defined Au Sites for the Hydrogen Evolution Reaction
ABSTRACT Surface metal‐organic frameworks (SMOFs) are promising platforms for catalysis, yet their structural response to electrochemical bias is often overlooked. We report the potential‐driven activation of an N‐heterocyclic carbene (NHC)‐based SMOF on Au(111) for the hydrogen evolution reaction (HER). Operando elect...