Author

Kami L. Hull

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Sep 2026

Reductive Catalyst Regeneration Enables the General Cu-Catalyzed Atom Transfer Radical Addition with Primary Alkyl Halides.

Primary alkyl halides are poor coupling partners in most atom transfer radical addition (ATRA) reactions due to their propensity to undergo off-cycle radical termination pathways, which lead to catalyst deactivation. Herein, we overcome this challenge in the Cu-catalyzed ATRA reaction though the addition of 1,1'-azobis...

Gyeongmin K. Lee, Tam D. Ho, Jacob A. Utley et al. · Organic Letters · 0 citations

Sep 2026

Synthesis of α-Halophosphonates via Copper-Catalyzed Atom Transfer Radical Addition.

α-Substituted alkylphosphonates and phosphates have broad utility in the pharmaceutical, agrochemical, and commodity chemical industries. Herein, we present the copper-catalyzed atom transfer radical addition (ATRA) of alkyl halides to alkenylphosphonates for the synthesis of α-halophosphonates enabled by 1,1'-azobis(c...

Jacob A. Utley, Tam D. Ho, B. Lee et al. · Organic Letters · 0 citations