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Sep 2026

Visible-Light-Mediated Tandem Heck-Type Arylation/[4+2] Electrocyclization Process to Access 9,10-Dihydronaphthalene.

Given their biological and synthetic importance, the construction of 9,10-dihydronaphthalene scaffolds is a pivotal transformation in organic synthesis, serving as a gateway to various bioactive natural products and functional materials. Herein, we develop a visible-light-driven, EDA-mediated Heck-type arylation/[4+2]...

Jing-Ying Liu, Ke-Yi Deng, Kai Chen et al. · 0 citations
Sep 2026

Mechanistic Insights Into Dirhodium‐Catalyzed Arylation of sp 2 C─H Bond: Reaction Profile, Ligand Effects, and Comparison With Diruthenium Catalysis

This study uses systematic density functional theory calculations to elucidate the mechanism of dirhodium/NHC‐catalyzed C─H arylation. In the Rh 2 (OAc) 4 /NHC system, C─H activation follows a stepwise pathway that involves oxidative addition to a Rh(I) center followed by acetate‐assisted deprotonation. The signi...

Ping Chen, Kai Chen · 0 citations

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