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Visible Light-Promoted γ-C(sp3)-H Acylation of Aliphatic Amines Enabled by N-Heterocyclic Carbene Organocatalysis.
The development of an environmentally benign protocol for the site-selective γ-C(sp3)-H acylation of aliphatic amines is of significant interest given their utility in accessing a diverse collection of γ-aminoketones prevalent in biologically active compounds. Herein, we report a visible-light-driven γ-C(sp3)-H acylati...