Vinylene-Linked Covalent Organic Frameworks with Subtly Tuned Stacking for Near-Infrared Light-Driven Photocatalysis of Organic Transformations.
Interlayer alignment holds a pivotal role for layered materials in tailoring their physical properties and chemical activities. Herein, we designed and synthesized a D2h-symmetric pyrene-derived monomer with four methyl substituents adjacent to the two nitrogen atoms embedded at the 2,7-positions of its molecular perip...