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Author

Jie Xu

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Open access Sep 2026

Asymmetric Radical-Type Clayden Rearrangement for the Synthesis of Enantiopure 1,2-Aminothiols and 1,2-Aminoalcohols

We report herein an expedient method for the construction of enantiopure 1,2-aminothiols and 1,2-aminoalcohols starting from polar amino acids cysteine and serine via a photoredox-catalyzed, decarboxylation-enabled asymmetric radical-type Clayden rearrangement. The strategy of “self-regeneration of stereocenters (SRS...

Sen Jiang, Jie Xu, Meng-Yao Zhang et al. · 0 citations

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