Hydrogen-Bonded Electron Donor-Acceptor Complex Enables Markovnikov Hydroarylation and Hydroxyalkylation of N-Acyl Enamines.
Visible-light-mediated electron donor-acceptor (EDA) complex catalysis has emerged as a powerful strategy for radical transformations under mild conditions, yet EDA donor catalytic systems driven by hydrogen bonding remain largely underexplored. Herein, we report a H-bonded EDA (H-EDA) donor catalysis system, employing...