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Oct 2026

Metal-Dependent Electron Transfer in Acidic UV/Peroxymonosulfate: Inner-Sphere Proton-Coupled Two-Electron Transfer Drives Ni(III)-Oxyl Formation Distinct from Cu Pathways

Nickel–ethylenediaminetetraacetic acid (Ni-EDTA) persists in electroplating wastewater due to strong metal–ligand coordination and is widely assumed to degrade via radical pathways during advanced oxidation processes (AOPs). Here, we show that its decomplexation in an acidic UV/peroxymonosulfate (UV/PMS) system is go...

W. Deng, Xiao-Li Lv, Ying-Qi Li et al. · 0 citations
Open access Aug 2026

JMJD5 Dioxygenase Inhibition Mechanism by 2-Hydroxyglutarate: A QM/MM Study

Jumonji domain-containing protein 5 (JMJD5) is a FeII/2-oxoglutarate-dependent oxygenase implicated in cellular metabolism and cancer-related processes. Although the oncometabolite 2-hydroxyglutarate (2-HG) is known to inhibit JMJD5, the molecular origin of this inhibition remains unclear. Here, molecular dynamics si...

Xue-Yi Ji, Ziyue Huang, Yingqi Li et al. · 0 citations

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