J. Ziller

Redox-Triggered Proton Transfer in Synthetic Models for Non-Heme Diiron Enzymes: Spectroscopic, Computational, and Mechanistic Insights

The transformations that occur at metalloenzyme active sites during catalysis are inextricably coupled to secondary-sphere interactions with surrounding amino acids and water molecules. Probing the elemental steps of these in vitro reactions remains a formidable challenge; their inherent catalytic velocity frequently...