Reduction Process of Pt(IV) Complexes With Axial Acetato Ligands by Ascorbic Acid; Comparison of Experimental and Computational Tools.
In the present work, the reduction mechanism of several Pt(IV) complexes bearing two axial acetato ligands by ascorbic acid (AA) was investigated. The computational approach is based on the grand-canonical formulation of the Gibbs-Alberty free energy, in which pH serves as an internal thermodynamic variable instead of...