Photoluminescent compounds showing distinct and selective optical response to external perturbation are essential components for sensing applications. Herein, we present a copper(I) iodide-sodium luminescent complex assembled with a hybrid phosphane-phosphinate ligand. The photoemission of the tetrametallic {Cu2I2Na2}...
Hennamaarit Korhonen, Dorota Głosz, M. Beliaeva et al.· Angewandte Chemie· 0 citations
ABSTRACT Overcoming the long‐standing trade‐off between efficiency and radiative rate in metal‐free phosphorescence remains a central challenge in molecular photophysics and is pivotal for the next‐generation optoelectronic technologies. Here, we demonstrate that tuning the strength of anion–π+ interactions in pyridini...
Eetu Hakkarainen, Corentin Montagne, Hao-Cheng Lin et al.· Angewandte Chemie· 0 citations
Externally stimulated ion motion within rigid crystalline matrices has significant potential to tune the functional properties of bulk materials but is difficult to control. Here, we report a diphosphonium diiodide that allows facile solid-state solvent-driven anion translocation, providing a direct optical readout of...
Eetu Hakkarainen, Pei-Ying Huang, Chen-Yu Lin et al.· Journal of the American Chem...· 0 citations
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