Interfacial Mn-Carbon Nitride Synergy Enables Selective Photocatalytic C─H Chlorination via Single-Atom Catalysis.
Single-atom photocatalysts offer a structurally defined platform for merging homogeneous and heterogeneous catalysis, yet their application in selective C─H functionalisation remains limited. In this study, we report a manganese-based single-atom photocatalyst (Mn@f-g-C3N4) comprising atomically dispersed Mn─Nx sites a...