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Open access Oct 2026

Cooperative Enantiomorphic-Site and Chain-End Chirality in Isoselective β-Lactone Polymerization

Polymer properties are profoundly impacted by tacticity, necessitating an understanding of the origins of stereocontrol to make high-performance materials. Recently, we reported that controlled incorporation of stereoerrors into trans-poly(3-hydroxy-2-methylbutyrate) (trans-PHMB) through the isoselective polymerizati...

Morgan S. Young, Yolanda Rusconi, Ethan B. Flanagan et al. · 0 citations
Open access Jul 2026

Systematic Catalyst Variation for Improved Stereoselective Epoxide Polymerization: Subtle Modifications Resulting in Superior Efficiency

Isotactic poly(propylene oxide) (iPPO) is a semicrystalline polyether that has emerged as a high-strength, photodegradable material for marine applications. To improve the accessibility of iPPO, catalysts with higher activity and selectivity are required. Using rational catalyst design informed by computational insight...

Bai-Hao Ren, Bryce M Lipinski, L. S. Morris et al. · 1 citation

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