Enantioselective Synthesis of Axial Chiral Aryl Isoquinolines via N‐Directed 3d Metal Catalysts: A Perspective
Axially chiral N‐heterobiaryls are important structural motifs in asymmetric catalysis, medicinal chemistry, and chiral functional materials. Their enantioselective synthesis has traditionally relied on noble‐metal catalysis or resolution‐based strategies, which often suffer from high cost, limited modularity, and rest...