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Sep 2026

Mechanism and Origins of Enantioselectivity of Rhodium-Catalyzed [4+3] Annulation of Benzosilacyclobutenes with 7-Oxabenzonorbornadienes.

Rhodium-catalyzed asymmetric [4+3] annulation of benzosilacyclobutenes with 7-oxabenzonorbornadienes provides an efficient route to enantioenriched seven-membered sila-heterocycles. In this study, density functional theory calculations were performed to elucidate the reaction mechanism and the origins of the enantiosel...

Deng Pan, Yue Shi, Xing-Wei Li et al. · 0 citations

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