Tuning Stiffness and Backbone Rigidity of Diels–Alder-Based Thermosets with Macrocyclic Telechelic Cyclopentadiene Monomers
Dynamic covalent polymer networks based on Diels–Alder (DA) chemistry provide a versatile platform for reprocessable and recyclable thermosets. While mechanical properties in these systems are typically tuned through cross-link density or chemical composition, the role of segmental mobility within network junctions h...