Rapid Flow Synthesis of Zr-MOF Nanoparticles in Supercritical CO2 for Toxic Chemical Removal.
Zirconium-based metal-organic frameworks (Zr-MOFs) are promising materials for the adsorption and degradation of toxic chemicals; however, their scalable synthesis is hindered by the slow formation of Zr-oxo clusters. Here, we report rapid flow synthesis of Zr-MOF nanoparticles in supercritical carbon dioxide (scCO2)....