Dual Triplet Ketone/Nickel Catalysis for the Cross-Coupling of Aryl/Alkyl Bromides with Alkyl Boronic Acids/Boronates through Radical Transfer Strategy.
In the present work, we have developed a dual triplet ketone/nickel-catalyzed strategy for C(sp3)-C(sp2) and C(sp3)-C(sp3) cross-coupling between aryl/alkyl bromides and alkyl boronic acids/boronates via an aminyl radical transfer (ART) strategy. The protocol features several attractive advantages, including mild react...