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Agathe Fayolle

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Open access Sep 2026

A unified strategy for α-alkoxyalkyl radical generation via pinacol boronic ester precursors

A general method to generate α-alkoxyalkyl radicals from pinacol boronic ester precursors (R–Bpin) has been developed. These radical precursors are stable in air, easy to prepare, and readily accessible via Matteson homologation followed by a 1,2-metallate shift with a broad range of metal alkoxides. The key step is a...

E. André-Joyaux, Lise Benoist, Agathe Fayolle et al. · 0 citations

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